电化学发光分析

BPCL在电化学发光分析领域中的应用 

电化学发光(Electrogenerated chemiluminescence, ECL)是在电极上施加一定的电压使电极反应产物之间或电极反应产物与溶液中某组分进行化学反应而产生的一种光辐射，其作为一种新的痕量分析手段越来越引人注目。BPCL在电化学分析领域的应用例子^[1-6]：

[1]     Liu X Q, Shi L H, Niu W X, LiH J, Xu G B. Environmentally Friendly and Highly Sensitive Ruthenium (II) Tris(2, 2′‐bipyridyl) Electrochemiluminescent System Using 2‐(Dibutylamino) ethanolas Co‐Reactant. Angewandte Chemie, 2007, 119(3): 425-428.

[2]     Qi L M, Xia Y, Qi W J, Gao WY, Wu F X, Xu G B. Increasing Electrochemiluminescence Intensity of a WirelessElectrode Array Chip by Thousands of Times Using a Diode for Sensitive VisualDetection by a Digital Camera. Analytical Chemistry, 2015, 88(2): 1123-1127.

[3]     Qi W J, Wu D, Zhao J M, Liu ZY, Zhang W, Zhang L, Xu G B. Electrochemiluminescence resonance energy transferbased on Ru(phen)₃²⁺-doped silica nanoparticles and itsapplication in “turn-on” detection of ozone. Analytical Chemistry, 2013, 85(6):3207-3212.

[4]     Tang X F, Zhao D, He J C, LiF W, Peng J X, Zhang M N. Quenching of the electrochemiluminescence of tris (2,2′-bipyridine) ruthenium (II)/tri-n-propylamine by pristine carbon nanotube andits application to quantitative detection of DNA. Analytical Chemistry, 2013,85(3): 1711-1718.

[5]     Zhang J, Chen P P, Wu X Y,Chen J H, Xu L J, Chen G N, Fu F F. A signal-on electrochemiluminescenceaptamer biosensor for the detection of ultratrace thrombin based onjunction-probe. Biosensors and Bioelectronics, 2011, 26(5): 2645-2650.

[6]     Wang D F, Li Y Y, Lin Z Y,Qiu B, Guo L H. Surface-enhanced electrochemiluminescence of Ru@SiO₂ for ultrasensitive detection of carcinoembryonic antigen. Analytical Chemistry,2015, 87(12): 5966-5972.

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